Study on the melt tension behavior of polyolefinic terblends to improve the processability of polypropylene

Document Type : Research Paper

Authors

1 Assosiate Professor of Chemistry, Payame Noor University, Iran.

2 M.A in Chemistry, Payame Noor University, Iran.

Abstract

Considering the good properties and price, PP (polypropylene) is a very important organic polymer with a wide application. However, because of its low elasticity and poor melt strength, the process is difficult to handle. In this work, the effect of blending with HDPE and EPDM on the high temperature properties of PP was studied. PP/HDPE/EPDM terblends having various compositions was prepared then the hot tensile and sagging tests were performed. The effects of composition, temperature and load speed were evaluated. Hot stress-strain behavior proved that at every temperature and speed, blending improved the properties of PP. All blends had the better elastic modulus, tensile strength and post yield modulus; hence the better processability than PP. The changes in temperature and load speed also affected the results. The sagging trend was improved in several blends as well. Totally, the blending will promoted the hot tension and the melt strength of PP.

Keywords


[1] Karger-Kocsis, J. (1999). Polypropylene, Kluwer Academic Publisher, London, 1st ed., 845-852.
 
[2] Throne, J.L. (1996). Technology of thermoforming, Carl hanser Verlag, Munich, 1st ed., chapter 9.
 
[3] Throne, JL. (1997). “Rapra Review Reports, Report 93”, Advances in Thermoforming, 8, 3-25.
 
[4] Hylton, D.C. & Cheng, C.Y. (1988). Plastics Engineering, 44, 55-57.
 
[5]. McHugh, K. & Ogale, K. (1990). “High Melt Strength Polypropylene for Melt Phase thermoforming”, SPE ANTEC, 452-455.
 
[6] Yoo, H.J. & Done, D. (1998). “Rheology of High Melt Strenght Polypropylene”, SPE ANTEC, 569-572.
[7] Lau, H.C., Bhattacharya, S.N. & Field, G.J. (2000). “Influence of rheological properties on the sagging of polypropylene and ABS sheet for thermoforming”, Polym. Eng. & Sci. 40, 1564-1570.
 
[8] Gotsis, A.D. & Zeevenhoven, B.L. (2004). “The Effect of Long Chain Branching on the Processability of polypropylene in Thermoforming”, Polym. Eng. and Sci., 44, 973-981.
 
[9] Auhl, D., Stange, J., Munstedt, H. & Beate, V. (2014). “Long Chain Branched polypropylene by electron beam irradiation and their rheological properties”, Macromolecules, 37, 9465-9472.
 
[10] Torres, F.G. & Bush, S.F. (2010). “Sheet extrusion and thermoforming of long glass fibre reinforced Polypropylene”, Composites Part A: Applied Science and Manufacturing, 31, 1289-1294.
 
[11] Bush, S.F., Torres, F.G. & Methven, J.M. (2009). “Rheological characterisation of descrete long glass fibre (LGF) reinforced Polypropylene”, Composites Part A: Applied Science and Manufacturing, 31, 1421-1431.
 
[12] Bhattacharyya, D., Bowis, M. & Jayaraman, K. (2013). “Thermoforming woodfibre-polypropylene composites sheet”, Composites Science and Technology, 63, 353-365.
 
[13] Takano, N., Zako, M., Fujitso, R. & Nishiyabu, K. (2014). “Study of large deformation characteristics of knitted fabric reinforced thermoplastic composites at forming themperature by digital image-based strain measurment technique”, Composites Science and Technology, 64, 2153-2163.
 
[14] Myers, J.H. (2005). “Polypropylene resins for sheeting and thermoforming”, Journal of Plastic film and sheeting, 1, 250-257.
 
[15] Malpass, V. & Kempthorn, J. (2016). “Setting conditions for polyolefin thermoforming”, Plastics Engineering, 42, 53-57.
 
[16] Machida, T. (2000). “Deep drawing of polypropylene sheets under differential heating conditions”, Polym. Eng. and Sci., 28, 405-412.
 
[17] Malpass, V., Kempthorn, J. & Dean, A. (2008). “Processing mineral filled polypropylenes for quality packaging”, ANTEC, 183-186.
 
[18] Malpass, V., Kempthorn, J. & Dean, A. (2012). “Estimating thermoforming behavior of mineral-filled polypropylenes”, Plastics Engineering, 45, 27-31.
 
[19] Maier, C. & Calafut, T. (1998). Polypropylene: The Definitive User's Guide and Databook, Plastics Design Library, New York, 1st ed., 234-235.
 
[20] Jacoby, P., Yang, J.C. & Kissel, W.J. (2004). “A new polypropylene resin with enhanced thermoformability”, SPE ANTEC, 865-871.
 
[21] Macauley, N., Harkin-Jones, E. & Murphy, W.R., (2006). “Thermoforming polypropylene”, Plastics Engineering, July 96, 33.
 
[22] Macauley, N., Harkin-Jones, E. & Murphy, W.R. (2017). “The influence of nucleating agents on the extrusion and thermoforming of polypropylene”, Polym. Eng. & Sci., 38, 516-523.
 
[23] Jacoby, P., Wu, J. & Heiden, M. (2000). “Thermoformable polypropylene- based sheet”, United States Patent, 5310584.
 
[24] Macauley, N., Harkin-Jones, E. & Murphy, W.R. (2007). “Method of assessing thermoformability of extruded polypropylene sheet, Plast”. Rubb. Composites Processing and Applications, 26, 165-171.
 
[25] Prosser, W., Hine, P.J. & Ward, I. M. (2000). “Investigation into thermoformability of hot compacted polypropylene sheet, Plast”. Rubb. and Composites, 29, 401-410.